Method and apparatus for making improved laminating film

ABSTRACT

A method and apparatus for manufacturing a film suitable for use in lamination under heat and pressure. A plurality of resins is co-extruded into concentric annuli, the inner annulus being a polyester type resin, and at least one of the outer annuli consisting of a polyolefin based resin. The co-extrusion is carried out as the extruding die is rotated about its axis. After quenching to form a multi-layer seamless tube, the tube is collapsed and heated to a temperature suitable for biaxial orientation. An air bubble is introduced into the heated tube to expand the diameter thereof and simultaneously orient the tube biaxially by molecular orientation. The biaxially oriented tube is cooled sufficiently to retain its molecular orientation, and is then collapsed. The tube is then heated to a shrinking temperature while under controlled restraint to achieve a predetermined dimension in amount of shrinkage in the film. Finally, the edges of the shrunk tube are slit to form a pair of flat films. 
     Additional improvements are achieved by including irradiation of the films by ultraviolet light, and by treating one of the film surfaces with a corona discharge.

This is a division, of application Ser. No. 391,874, filed June 24,1982.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention is in the field of manufacturing film suitable foruse as laminating film and involves coextrusion of a plurality of filmsof different chemical composition, biaxially orienting the same,subjecting the biaxially oriented tube to controlled sizing conditions,and then forming a pair of flat films from the tube.

2. Description of the Prior Art

Various types of heat-activated lamination systems have been usedcommercially for many years. Such systems are usually used forencapsulating and sealing of documents between two plastic films toprotect documents and to enhance the visual appearance. Suchpost-lamination is usually performed in offices, schools, or graphic artshops. In the case of laminating identification cards, licenses, and thelike, there are often stringent specifications and consistent highquality results are required.

The laminating films used in this type of lamination procedure usuallyconsist of one layer of unoriented polyethylene or a copolymer thereof,and another layer of oriented and heat-set polyethylene terephthalate(PET). Typically, these materials are prepared by an extrusion coatingof polyethylene or its copolymers onto an oriented PET film web.

The extrusion processes commonly used to produce packaging films,although producing usable laminating films, provide several inherentdrawbacks. For one, hazy streaks and bubbles occasionally will occur asa result of contact with the hot shoes. These streaks and bubbles arecaused by air bubbles which are trapped at the interface between the twolayers during the coating operation. Such bubbles are usuallymicroscopic in size but they expand into larger bubbles and cause visualdefects such as streaks when subjected to certain heating conditions inthe lamination step. This phenomenon only occurs from time to time. Ithas been known that it is influenced by process conditions, but it hasnot been known how to predictably cure it.

Heated roll laminators also have their own disadvantages, particularlythe creation of wrinkles and the presence of uneven heating. Forpost-lamination applications, it is desirable that the film shouldshrink minutely in the transverse direction when heated so as to smoothout the film which, in turn, insures uniform heating. Laminating filmproduced by existing extrusion coating operations occasionally willexhibit positive dimensional change in the transverse direction of thefilm when heated. Although the amount of change is very small, it isvery undesirable since it causes the film to wrinkle and to be heatedunevenly. The reasons for this transverse growth are believed to betwofold. In the extrusion coating operation, the PET is usually heatedto drive off the solvent or water from the primers. At the same time,the film is necessarily under tension in the machine direction (MD) toavoid wrinkles and the like. This combination of conditions tends tocause tensile stress in the PET film in the machine direction, and, dueto the poisson's ratio of the material, a certain amount of compressionstress is also effected in the transverse direction of the film. Thestresses are frozen-in when film is cooled under tension. When the filmis re-heated in the post-lamination step, the stresses are relieved tocause MD shrinkage and transverse growth.

Moreover, the PET film when produced by conventional flat castprocedures tends to have low transverse shrinkage which contributes tothe aforementioned transverse growth problem.

Another drawback existing in conventional laminating film is inadequateinterfacial adhesion for certain applications. In the manufacture ofidentification cards, outdoor signs, and the like, the resultinglaminates must possess excellent interfacial adhesion in laminatingfilms but must also be resistant to environmental influences such ashigh humidity, rain, and the like. This requirement is not met byexisting laminating film technology. Although many water-resistantprimers are available, they all contain residual low molecular weightfractions which, upon heating in the lamination step, tend to migratethrough the polyethylene layer to the surface, causing a weakeningeffect on the adhesion of the laminate to the underlying document.

Another defect results from the fact that in postlaminating, the film isalways contact heated either by means of heated rollers or by heatedshoes. Uniform heating therefore depends on uniform contact. Thepresence of gauge bands which are inherent in flat die-casting andcoating processes cause uneven contact, and thus cause uneven heating.Although good quality control on existing processes can reduce thisproblems, it cannot be eliminated completely.

There are numerous examples of multi-ply laminating films in thepatented prior art, of which the following are believed to be typicalexamples.

Bornstein et al. U.S. Pat. No. 4,064,296 describes a heat shrinkable,multi-layer film including a layer of a hydrolyzed ethylene-vinylacetate copolymer formed by co-extruding the hydrolyzed ethylene-vinylacetate copolymer layer between two other polymeric layers whichthemselves may be ethylene-vinyl acetate copolymers. The resultinglaminated structure is thereafter irradiated and oriented to produce afilm which is heat shrinkable and is said to have very low oxygenpermeability.

Schirmer U.S. Pat. No. 4,095,012 describes a process for producingoriented films and laminates from nylon 66 and blends thereof wherein anylon layer is co-extruded between layers of polymeric materials such aspolyolefins and their copolymers to form a laminate. After quenching ofthe laminate, the laminated structure is oriented biaxially.

In U.S. Pat. No. 4,151,328 to Kight there is described a packagingmaterial film including a self-adhering layer composed of a terpolymerof ethylene, a vinyl ester, and an alkenoic acid. This layer is appliedonto a plasticized saran.

Mueller et al. in U.S. Pat. No. 4,188,443 describe a multi-layerpolyester/polyolefin shrink film consisting preferably of five layers inwhich the middle layer is a polyester or copolyester, the two innerlayers adjacent the middle layer are both ethylene-vinyl acetatecopolymers, and the skins or outer layers are ethylene-propylenecopolymers. This patent describes biaxial stretching of the two by meansof internal air pressure to form a bubble.

U.S. Pat. No. 4,197,326 to Wakamatsu et al. describes a packaging tubecomposed of an oriented laminated film formed by stretching a compositefilm having an inner layer composed of an oxygen barrier thermoplasticresin confined between outer layers of a thermoplastic resin having asmaller water absorption capability than the inner layer. The oxygenbarrier layer may be materials such as polyamides, PET, hydrolyzedethylene-vinyl acetate copolymers (EVA) and polyvinyl alcohol whereasthe thermoplastic resin outer films are composed of materials such aspolyethylene, EVA, or polybutene.

Andrews et al. U.S. Pat. No. 4,198,256 describes a heat-sealableoriented plastic film consisting of an oriented polypropylene filmcovered with a heat-sealable layer consisting of a predominantly linearrandom copolymer of ethylene with an additional alpha-olefin having atleast three carbon atoms per molecule.

In U.S. Pat. No. 4,198,458 to Mitsuishi et al. there is described astretch-oriented laminate polyester film consisting of two or threelayers of polyester films of different intrinsic viscosities. Thepreferred embodiment of the invention consists of a stretch-orientedlaminated film and a magnetic layer coated on an external surfacethereof to provide a magnetic recording medium.

U.S. Pat. No. 4,274,900 to Mueller et al. describes a multi-layerpolyester/polyolefin shrink film preferably having five layers in whichthe middle layer is a polyester or copolyester, the two inner adjacentlavers are EVA copolymers, and the skin or outer layers compriseethylene-propylene copolymers.

SUMMARY OF THE INVENTION

The present invention provides a method of manufacturing a film suitablefor use in lamination under heat and pressure which eliminates many ofthe objectionable features of laminating films of the prior art.Specifically, the method of the present invention in its broader aspectsinvolves co-extruding concentric annuli of a polyester such as PET asthe inner annulus and a polyolefin-based resin as the outer annuluswhile rotating the annuli about their common axis during extrusion. Theextrusion is carried out in the absence of air at the interface betweenthe two annuli. In the next step, the extrudate is quenched to form amulti-layer seamless tube which is thereupon collapsed and heated to atemperature in excess of the glass transition temperature, which issuitable for biaxial orientation. In the next step, an air bubble isintroduced into the heated tube to expand the diameter thereof to adiameter greater than that of the original extrudate to thereby orientthe tube biaxially by molecular orientation. This biaxially orientedtube is cooled sufficiently to retain its molecular orientation and thencollapsed. The tube is then heated to a relatively high heat-setshrinking temperature while restraining shrinkage thereof to apredetermined, sized, dimension and finally the thus shrunk film is slitat the edges to form a pair of flat films. Additional benefits areachieved by irradiating the films by ultraviolet light during and/orafter the controlled shrinkage step to enhance the interfacial adhesion.In addition, the slitting of the tube into flat films is advantageouslyfollowed by a treatment of the film surfaces in a texturizing processwhich roughens the surface of the film, and in turn, is followed bytreatment with a corona discharge.

The particularly preferred form of the present invention involvesco-extrusion of three annuli, the PET resin constituting the innerannulus, and different EVA resins constituting the middle and outerannuli.

The present invention also provides an improved laminating film and anend product and also an improved film tube spreader and support whichprovides the controlled amount of shrinkage in the tube prior toslitting.

The laminating film of the present invention has no entrapped airbubbles at the interface of the layers because the layers areco-extruded and the interface is never in contact with air. Thiseliminates visual defects such as streaks caused by entrapped bubbles.

The improved film has desirable transverse shrinkage and never exhibitsundesired transverse growth because of the novel co-extrusion andco-orientation process. In accordance with this process, solvent orwater drying is eliminated, and the machine direction stress under heatis also eliminated. Furthermore, it was found that the process of thepresent invention produces films with increased amount of transverseshrink to start with. This combination eliminates the transverse growthand the wrinkles and uneven heating caused by it.

Delamination problems are also eliminated and interfacial adhesion whichis insensitive to the environment is provided between the film layers.

The oscillation or rotation of the extrusion dies and other hardware inthe manufacture of the film virtually eliminates the gauge band problem,and thus eliminates the uneven heating and wrinkling problems associatedwith it.

BRIEF DESCRIPTION OF THE DRAWINGS

The drawings illustrate a preferred form of apparatus for use in theprocess of the present invention and are identified as follows:

FIG. 1 is a somewhat schematic showing of an overall production lineembodying the improvements of the present invention;

FIG. 2 is a cross-sectional view on an enlarged scale illustrating aportion of one embodiment of the co-extrusion mechanism in accordancewith the present invention;

FIG. 3 is a cross-sectional view taken substantially along the lineIII--III of FIG. 2;

FIG. 4 is a cross-sectional view taken substantially along the lineIV--IV of FIG. 2;

FIG. 5 is a view taken substantially along the line V--V of FIG. 1;

FIG. 6 is a view taken substantially along the line VI--VI of FIG. 5;

FIG. 7 is a view taken substantially along the line VII--VII of FIG. 5;and

FIG. 8 is a broken-away view ilustrating the three-ply laminating filmof the present invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

In FIG. 1, reference numeral 10 indicates generally a coextrusionapparatus for use in accordance with the principles of the presentinvention. It includes a distribution ring 11 which is fed by threenozzles, a centrally disposed nozzle 12 which injects the PET resin, andside nozzles 13 and 14 which are used to inject the materials which areto be laminated to the central annulus of PET. For example, the materialinjected through the nozzle 13 which forms the middle annulus of thethree-ply structure may be EVA containing about 8% by weight vinylacetate. The resin injected through the nozzle 14 may, for example, beEVA having a 4% vinyl acetate concentration. The outside layer serves tobond itself more securely to the underlying substrate, while thematerial of the middle layer serves to bind the outer EVA layer to theinner PET layer. The PET function as an ultraviolet absorbing layer,while the EVA layers are ultraviolet transmitting layers. In place ofthe PET, other high temperature resisting materials such aspolycarbonate resins, polybutene terephthalate resins, and the like, canbe employed.

In place of the EVA, other olefinic resins such as ethylenic copolymersincluding ionomers can be employed.

One embodiment of the die arrangement is illustrated in FIG. 2. There,the distributing head 11 is fixedly mounted on a support 15. It is alsoprovided with an air inlet pipe 16 for forming the co-extrudates intothe form of a tube 17 during coextrusion. The air inlet pipe 16communicates with a centrally disposed passage 18 in a centrallydisposed rotatable extrusion head 19. The extrusion head 19 may berotated during extrusion by various means. As illustrated, a drive gear20 engages teeth 21 formed in the exterior of the extrusion head 19. Abearing 22 permits relative rotation between the extrusion head 19 andthe distributor head 11.

As best seen in FIG. 3, the three resinous compositions are delivered toarcuate segments 12a, 13a, and 14a, respectively, at the top of therotating extrusion head 19. These arcuate slots merge into continuousannular rings 12b, 13b, and 14b, respectively, at the base of therotatable extrusion head 19, so that upon extrusion, continuous annuli12c, 13c and 14c are co-extruded as best seen in FIG. 4. Since theextruding surfaces come together in the absence of air, there is nopossibility of entrapping air bubbles which could lead to streaks.

Returning to FIG. 1, the extruded tube 17 while still hot is passedthrough a water ring 25 to quench the external surface of the extrudedtube 17. The water is sufficiently cold to fastquench the tube andreduce crystallinity in the PET so that the PET either stays amorphousor has low crystallinity (less than 25%). Additional water quenching iseffected by a plurality of water spray devices 26 as the tube iscollapsed between a pair of nip rollers 27 and 28. During passagebetween the rollers 27 and 28, water is stripped from the exteriorsurface of the extruded tube and falls into a pan 29. Additional amountsof water are stripped from the tube by training the same over a roller30 and contacting the tube with air jets 31 which blow the remainingsurface water down into a collecting pan 32.

The dried extruded tube is then guided by means of rollers 33, 34, and35 into an extrusion tower generally indicated at reference numeral 36.Within the tower, the flattened tube passes between a pair of niprollers 37 and 38 which further flatten the same and then through aniris 39. The interior of the tube is reopened at this point, by airinside the tube. As it is reopened, the tube passes through a heater 40in which it is heated to a temperature suitable for biaxial orientation.Such temperature is usually in excess of the glass transitiontemperature of PET. If necessary, an air ring 41 can be provided toadjust the neck of the tube to a temperature most suitable for biaxialorientation.

Air trapped within the tube serves to form a bubble within the tubewhich causes the tube to expand to a diameter about three to four timesthe diameter of the orignal extruded tube 17, forming an enlargeddiameter tube 42 which is biaxially oriented. The tube then passesthrough a cooling air ring 43 which reduces the temperature on the tube,before it is again collapsed by passing through a collapsing frame 44and then into the nip between a pair of rollers 45 and 46.

After passing between rollers 47, the flattened tube is then subjectedto controlled heat-set and ultraviolet irradiation. The heat-set isaccomplished by means of a heater-spreader generally indicated atreference numeral 48 and shown in detail at FIGS. 5 to 7, inclusive.

The spreader consists of a pair of conduits 49 and 50 in spacedcantilevered relation as seen in FIG. 7. The spacing between the twoconduits 49 and 50 is controlled by a pair of frame members 51 and 52,respectively, connected to the two conduits. The spacing between theframe members is controlled by means of adjusting means 53 and 54extending between the two frame members. The ends of the frame members51 and 52 are received in sliding relation along a pair of rods 55 and56.

A coolant such as water is circulated through each of the conduits 49and 50. A water inlet pipe 57 serves to introduce the circulating waterinto the conduit 49, and discharge line 58 is provided to return thecoolant to the source. Similarly, a water inlet line 59 and a dischargeline 60 are provided for circulating cooling water through the conduit50.

The flattened tube is fitted over the spreader 48 and may be opened bythe introduction of air through air lines 61 and 62. The tube is thusslightly distended in being pulled over the spreader which prevents itfrom shrinking beyond a controlled amount.

The tube as it enters the spreader 48 has a room temperature but isheated to a heat-set temperature of about 400° F., above the highesttemperatures used in expected subsequent lamination processes in whichthe film will be used. All the time the tube is on the spreader, it isunder longitudinal tension provided by take-up rollers 63 and 64 (FIG.1).

A pair of arcuate guides 65 and 66 is provided beyond the end of thespreader to provide guide means for directing the tube for the slittingoperation. Slitting knives 67 and 68 are fixedly secured to slides 69and 70, respectively, which slides are adjustably positionable by beingslidably mounted on the rods 55 and 56 as shown in FIG. 5. Relativeposition of the slides 69 and 70 dictates the position in which theslitting knives 67 and 68 sever the elongated tube into a pair of flatface-to-face films.

Before the flat films are cooled down below 230° F., they are subjectedto irradiation by banks 72 and 73 of ultraviolet lights. These lightsserve to improve the adhesion between the layers making up the films.

After treatment with the ultraviolet light, the films may be texturizedon their outwardly facing surfaces by passing the same into contact withrollers 74 for one of the surfaces and rollers 75 for the other. Thesetexturizing rollers are used to create a rough surface on the EVA sideof the film. The rough surface is desirable for eliminating air bubblesand the like and helps winding up the same on the rolls.

Following the texturizing, the films may be subjected to treatment in azone 76 in which a corona discharge device is located. This techniqueprovides enhancement of adhesion to the substrate in post-laminationoperations.

The final product is illustrated in FIG. 8 of the drawings. The interiorlaminate 81 comes in contact with the substrate and consists of aroughened, corona treated EVA film. Tightly secured to the film 81 isthe intermediate binder film 82 consisting of an EVA polymer having ahigher content of vinyl acetate than the film 81. Finally, the outerfilm 83 consists of oriented, heat-set PET of good optical clarity.

The present invention provides a film which still retains sometransverse shrinkage property making it ideally suited for use inpost-lamination procedures. In most other applications for oriented,heat-set PET films, it is usually desirable to minimize the shrinkage,not to encourage it.

Although co-extrusion has been known in some cases to provide a film ofgood clarity, such co-extrusion is used in the present instance toeliminate the heat-activated bubbling problem which has been verytroublesome.

Moreover, although ultraviolet light at elevated temperatures is knownto enhance adhesion between certain layers of plastic materials, it isfound that in this case, the ultraviolet light has to be used after theorientation step to be effective. When ultraviolet light is used beforeorientation, the adhesion achieved is almost completely lost afterorientation.

It should be evident that various modifications can be made to thedescribed embodiments without departing from the scope of the presentinvention.

I claim as my invention:
 1. The method of manufacturing a film suitablefor use in lamination under heat and pressure which comprises:(1)co-extruding concentric annuli of a polyester as the inner annulus and apolyolefin based resin as the outer annulus while rotating said annuliabout their common axis during extrusion, (2) quenching the extrudate toform a multi-layer seamless tube, (3) heating the tube to a temperaturesuitable for biaxial orientation, (4) providing an air bubble in theheated tube to expand the diameter thereof to a diameter greater thanthat of the original extrudate to thereby orient the tube biaxially bymolecular orientation, (5) cooling the biaxially oriented tubesufficiently to retain its molecular orientation, (6) collapsing thetube, (7) heating the tube to a heat-set temperature in excess of thetemperature at which the film is to be laminated while restrainingshrinkage thereof to a predetermined dimension, and (8) slitting theedges of the tube to form a pair of flat films which retain sometransverse shrinkage properties.
 2. A method according to claim 1 inwhich: said polyester resin is polyethylene terephthalate.
 3. A methodaccording to claim 1 in which: said polyolefin based resin is anethylene-vinyl acetate copolymer.
 4. A method according to claim 1 inwhich: irradiation of the films by ultraviolet light to enhance theinterfacial adhesion is incorporated in step (7) when film temperatureis above 230° F.
 5. A method according to claim 1 in which: the slittingof step (8) is followed by texturizing treatment of the olefinic filmsurface.
 6. A method according to claim 5 in which: the treatment of theolefinic film surface is followed by treatment of the surface of theslit film with corona discharge.
 7. The method of manufacturing a filmsuitable for use in lamination under heat and pressure whichcomprises:(1) co-extruding concentric annuli of a polyester resin as theinner annulus, an adhesive, polyolefin based resin as a middle annulus,and a polyolefin based resin having adhesive properties toward thedesired substrate as the outer annulus while rotating said annuli abouttheir common axis during extrusion, (2) quenching the extrudate to forma three-layer seamless tube, (3) collapsing the tube, (4) heating thecollapsed tube to a temperature suitable for biaxial orientation, (5)providing an air bubble in the heated tube to expand the diameterthereof to a diameter greater than that of the original extrudate totherebv orient the tube biaxially by molecular orientation, (6) coolingthe biaxially oriented tube sufficiently to retain its molecularorientation, (7) collapsing the tube, (8) heating the tube to a heat-settemperature in excess of the temperature at which the film is to belaminated while restraining shrinkage thereof to a predetermineddimension, and (9) slitting the edges of the tube to form a pair of flatfilms which retain some transverse shrinkage properties.
 8. A methodaccording to claim 7 wherein said inner annulus is composed ofpolyethylene terephthalate, said middle annulus is composed of anethylene-vinyl acetate copolymer, and said outer annulus is composed ofan ethylene-vinyl acetate copolymer having a smaller proportion of vinylacetate than said middle annulus.
 9. A method according to claim 7 inwhich: irradiation of the films by ultraviolet light to enhance theinterfacial adhesion is incorporated in step (8) when film temperatureis above 230° F.
 10. A method according to claim 7 in which: theslitting of step (9) is followed by texturizing of the olefinic filmsurface.
 11. A method according to claim 10 in which: the film surfaceis treated with a corona discharge.
 12. An apparatus for manufacturing alaminating film which comprises:a co-extrusion head arranged to extrudea plurality of coaxial abutting annuli of differing compositions, meansfor rotating said co-extrusion head during such extrusion, quenchingmeans disposed beyond said co-extrusion head and arranged to quench theextrudate leaving said coextrusion head, first pressure rollers locatedbeyond said quenching means and arranged to flatten the extruded andquenched annuli into a multi-layer seamless tube, first heater meansreceiving the flattened tube and arranged to heat said tube to a biaxialorientation temperature, means for expanding the heated flattened tubeto a diameter greater than that of said annuli while simultaneouslybiaxially orienting the same, cooling means positioned to cool thebiaxially oriented tube sufficiently to control the orientation layer,second pressure rollers located beyond said cooling means and arrangedto flatten the biaxially oriented tube, second heater means locatedbeyond said second pressure rollers and arranged to heat the flattenedtube to a heat-set temperature, a spreader positionable inside saidflattened tube and arranged to support the tube and limit the amount offilm shrinkage induced by said second heater means, and slitter meansfollowing said spreader arranged to slit said tube along its edges intoa pair of flat films.
 13. An apparatus according to claim 12 whichincludes: ultraviolet irradiation means disposed within said spreaderfor enhancing the interfacial adhesion of the film.
 14. An apparatusaccording to claim 12 which includes: a corona discharge device locateddownstream of said slitter means and positioned to treat a surface ofthe films.
 15. An apparatus according to claim 14 which includes:atexturizing means immediately preceding said coronaa discharge means andarranged to roughen the outer surface of the film.
 16. The method ofclaim 1 wherein said heat-set temperature is about 400° F.
 17. Themethod of claim 7 wherein said heat-set temperature is about 400° F. 18.The apparatus of claim 12 wherein said heat-set temperature is about400° F.